Surface-confined [2 + 2] cycloaddition towards one-dimensional polymers featuring cyclobutadiene units

Bay V. Tran, Tuan Anh Pham, Michael Grunst, Milan Kivala, Meike Stöhr

OnderzoeksoutputAcademicpeer review

20 Citaten (Scopus)
363 Downloads (Pure)

Samenvatting

Surface-confined synthesis has been offering a wide range of opportunities for the construction of novel molecular nanostructures. Exploring new types of on-surface coupling reactions is considered essential for being able to deliberately tune the materials properties. Here, we report on the formation of a covalent C–C bonding motif, namely 1,3-cyclobutadiene, via surface-confined [2 + 2] cycloaddition between pyrene moieties using low temperature scanning tunneling microscopy (LT-STM) and X-ray photoemission spectroscopy (XPS) measurements. By employing a hydrogen dosing treatment together with low-temperature activation, we were able to both eliminate residual byproducts and obtain covalent 1D polymers through the formation of 1,3-cyclobutadiene units. The resulting C–C bonding motif has so far hardly been explored in surface chemistry and substantial evidence is provided that the hydrogen treatment is crucial towards the removal of byproducts in surface-confined polymerization.
Originele taal-2English
Pagina's (van-tot)18305-18310
Aantal pagina's6
TijdschriftNanoscale
Volume9
Vroegere onlinedatum10-nov-2017
DOI's
StatusPublished - 2017

Citeer dit