Synthesis and detection of a seaborgium carbonyl complex

J. Even; A. Yakushev; Ch E. Duellmann; H. Haba; M. Asai; T. K. Sato; H. Brand; A. Di Nitto; R. Eichler; F. L. Fan; W. Hartmann; M. Huang; E. Jaeger; D. Kaji; J. Kanaya; Y. Kaneya; J. Khuyagbaatar; B. Kindler; J. V. Kratz; J. Krier; Y. Kudou; N. Kurz; B. Lommel; S. Miyashita; K. Morimoto; K. Morita; M. Murakami; Y. Nagame; H. Nitsche; K. Ooe; Z. Qin; M. Schaedel; J. Steiner; T. Sumita; M. Takeyama; K. Tanaka; A. Toyoshima; K. Tsukada; A. Tuerler; I. Usoltsev; Y. Wakabayashi; Y. Wang; N. Wiehl; S. Yamaki

doi:10.1126/science.1255720

Synthesis and detection of a seaborgium carbonyl complex

J. Even, A. Yakushev, Ch E. Duellmann^*, H. Haba, M. Asai, T. K. Sato, H. Brand, A. Di Nitto, R. Eichler, F. L. Fan, W. Hartmann, M. Huang, E. Jaeger, D. Kaji, J. Kanaya, Y. Kaneya, J. Khuyagbaatar, B. Kindler, J. V. Kratz, J. KrierY. Kudou, N. Kurz, B. Lommel, S. Miyashita, K. Morimoto, K. Morita, M. Murakami, Y. Nagame, H. Nitsche, K. Ooe, Z. Qin, M. Schaedel, J. Steiner, T. Sumita, M. Takeyama, K. Tanaka, A. Toyoshima, K. Tsukada, A. Tuerler, I. Usoltsev, Y. Wakabayashi, Y. Wang, N. Wiehl, S. Yamaki

^*Corresponding author voor dit werk

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Experimental investigations of transactinoide elements provide benchmark results for chemical theory and probe the predictive power of trends in the periodic table. So far, in gas-phase chemical reactions, simple inorganic compounds with the transactinoide in its highest oxidation state have been synthesized. Single-atom production rates, short half-lives, and harsh experimental conditions limited the number of experimentally accessible compounds. We applied a gas-phase carbonylation technique previously tested on short-lived molybdenum (Mo) and tungsten (W) isotopes to the preparation of a carbonyl complex of seaborgium, the 106th element. The volatile seaborgium complex showed the same volatility and reactivity with a silicon dioxide surface as those of the hexacarbonyl complexes of the lighter homologs Mo and W. Comparison of the product's adsorption enthalpy with theoretical predictions and data for the lighter congeners supported a Sg(CO)(6) formulation.

Originele taal-2	English
Pagina's (van-tot)	1491-1493
Aantal pagina's	3
Tijdschrift	Science
Volume	345
Nummer van het tijdschrift	6203
DOI's	https://doi.org/10.1126/science.1255720
Status	Published - 19-sep.-2014

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Even, J., Yakushev, A., Duellmann, C. E., Haba, H., Asai, M., Sato, T. K., Brand, H., Di Nitto, A., Eichler, R., Fan, F. L., Hartmann, W., Huang, M., Jaeger, E., Kaji, D., Kanaya, J., Kaneya, Y., Khuyagbaatar, J., Kindler, B., Kratz, J. V., ... Yamaki, S. (2014). Synthesis and detection of a seaborgium carbonyl complex. Science, 345(6203), 1491-1493. https://doi.org/10.1126/science.1255720

@article{0e8fc46404504b2fba909cf48c5b0e27,

title = "Synthesis and detection of a seaborgium carbonyl complex",

abstract = "Experimental investigations of transactinoide elements provide benchmark results for chemical theory and probe the predictive power of trends in the periodic table. So far, in gas-phase chemical reactions, simple inorganic compounds with the transactinoide in its highest oxidation state have been synthesized. Single-atom production rates, short half-lives, and harsh experimental conditions limited the number of experimentally accessible compounds. We applied a gas-phase carbonylation technique previously tested on short-lived molybdenum (Mo) and tungsten (W) isotopes to the preparation of a carbonyl complex of seaborgium, the 106th element. The volatile seaborgium complex showed the same volatility and reactivity with a silicon dioxide surface as those of the hexacarbonyl complexes of the lighter homologs Mo and W. Comparison of the product's adsorption enthalpy with theoretical predictions and data for the lighter congeners supported a Sg(CO)(6) formulation.",

keywords = "TRANSITION-METAL, SG(CO)(6), CHEMISTRY, ELEMENTS",

author = "J. Even and A. Yakushev and Duellmann, {Ch E.} and H. Haba and M. Asai and Sato, {T. K.} and H. Brand and {Di Nitto}, A. and R. Eichler and Fan, {F. L.} and W. Hartmann and M. Huang and E. Jaeger and D. Kaji and J. Kanaya and Y. Kaneya and J. Khuyagbaatar and B. Kindler and Kratz, {J. V.} and J. Krier and Y. Kudou and N. Kurz and B. Lommel and S. Miyashita and K. Morimoto and K. Morita and M. Murakami and Y. Nagame and H. Nitsche and K. Ooe and Z. Qin and M. Schaedel and J. Steiner and T. Sumita and M. Takeyama and K. Tanaka and A. Toyoshima and K. Tsukada and A. Tuerler and I. Usoltsev and Y. Wakabayashi and Y. Wang and N. Wiehl and S. Yamaki",

year = "2014",

month = sep,

day = "19",

doi = "10.1126/science.1255720",

language = "English",

volume = "345",

pages = "1491--1493",

journal = "Science",

issn = "0036-8075",

publisher = "AMER ASSOC ADVANCEMENT SCIENCE",

number = "6203",

}

Even, J, Yakushev, A, Duellmann, CE, Haba, H, Asai, M, Sato, TK, Brand, H, Di Nitto, A, Eichler, R, Fan, FL, Hartmann, W, Huang, M, Jaeger, E, Kaji, D, Kanaya, J, Kaneya, Y, Khuyagbaatar, J, Kindler, B, Kratz, JV, Krier, J, Kudou, Y, Kurz, N, Lommel, B, Miyashita, S, Morimoto, K, Morita, K, Murakami, M, Nagame, Y, Nitsche, H, Ooe, K, Qin, Z, Schaedel, M, Steiner, J, Sumita, T, Takeyama, M, Tanaka, K, Toyoshima, A, Tsukada, K, Tuerler, A, Usoltsev, I, Wakabayashi, Y, Wang, Y, Wiehl, N & Yamaki, S 2014, 'Synthesis and detection of a seaborgium carbonyl complex', Science, vol. 345, nr. 6203, blz. 1491-1493. https://doi.org/10.1126/science.1255720

TY - JOUR

T1 - Synthesis and detection of a seaborgium carbonyl complex

AU - Even, J.

AU - Yakushev, A.

AU - Duellmann, Ch E.

AU - Haba, H.

AU - Asai, M.

AU - Sato, T. K.

AU - Brand, H.

AU - Di Nitto, A.

AU - Eichler, R.

AU - Fan, F. L.

AU - Hartmann, W.

AU - Huang, M.

AU - Jaeger, E.

AU - Kaji, D.

AU - Kanaya, J.

AU - Kaneya, Y.

AU - Khuyagbaatar, J.

AU - Kindler, B.

AU - Kratz, J. V.

AU - Krier, J.

AU - Kudou, Y.

AU - Kurz, N.

AU - Lommel, B.

AU - Miyashita, S.

AU - Morimoto, K.

AU - Morita, K.

AU - Murakami, M.

AU - Nagame, Y.

AU - Nitsche, H.

AU - Ooe, K.

AU - Qin, Z.

AU - Schaedel, M.

AU - Steiner, J.

AU - Sumita, T.

AU - Takeyama, M.

AU - Tanaka, K.

AU - Toyoshima, A.

AU - Tsukada, K.

AU - Tuerler, A.

AU - Usoltsev, I.

AU - Wakabayashi, Y.

AU - Wang, Y.

AU - Wiehl, N.

AU - Yamaki, S.

PY - 2014/9/19

Y1 - 2014/9/19

N2 - Experimental investigations of transactinoide elements provide benchmark results for chemical theory and probe the predictive power of trends in the periodic table. So far, in gas-phase chemical reactions, simple inorganic compounds with the transactinoide in its highest oxidation state have been synthesized. Single-atom production rates, short half-lives, and harsh experimental conditions limited the number of experimentally accessible compounds. We applied a gas-phase carbonylation technique previously tested on short-lived molybdenum (Mo) and tungsten (W) isotopes to the preparation of a carbonyl complex of seaborgium, the 106th element. The volatile seaborgium complex showed the same volatility and reactivity with a silicon dioxide surface as those of the hexacarbonyl complexes of the lighter homologs Mo and W. Comparison of the product's adsorption enthalpy with theoretical predictions and data for the lighter congeners supported a Sg(CO)(6) formulation.

AB - Experimental investigations of transactinoide elements provide benchmark results for chemical theory and probe the predictive power of trends in the periodic table. So far, in gas-phase chemical reactions, simple inorganic compounds with the transactinoide in its highest oxidation state have been synthesized. Single-atom production rates, short half-lives, and harsh experimental conditions limited the number of experimentally accessible compounds. We applied a gas-phase carbonylation technique previously tested on short-lived molybdenum (Mo) and tungsten (W) isotopes to the preparation of a carbonyl complex of seaborgium, the 106th element. The volatile seaborgium complex showed the same volatility and reactivity with a silicon dioxide surface as those of the hexacarbonyl complexes of the lighter homologs Mo and W. Comparison of the product's adsorption enthalpy with theoretical predictions and data for the lighter congeners supported a Sg(CO)(6) formulation.

KW - TRANSITION-METAL

KW - SG(CO)(6)

KW - CHEMISTRY

KW - ELEMENTS

U2 - 10.1126/science.1255720

DO - 10.1126/science.1255720

M3 - Article

SN - 0036-8075

VL - 345

SP - 1491

EP - 1493

JO - Science

JF - Science

IS - 6203

ER -

Synthesis and detection of a seaborgium carbonyl complex

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