Samenvatting
Cp*La(OAr)2 (Cp* = η5-C5Me5) is easily accessible by the reaction of La(OAr)3 with Cp*Li. Addition of THF yields the adduct Cp*La(OAr)2(THF)2. Both compounds disproportionate in solution with formation of equilibrium mixtures with comparable amounts of Cp*La(OAr)2, La(OAr)3 and Cp*2LaOAr. The equilibria were studied at various temperatures and thermodynamic parameters were determined from the temperature dependence of the equilibrium constants.
Originele taal-2 | English |
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Pagina's (van-tot) | 226-229 |
Aantal pagina's | 4 |
Tijdschrift | Recueil des Travaux Chimiques des Pays-Bas-Journal of the Royal Netherlands Chemical Society |
Volume | 109 |
Nummer van het tijdschrift | 3 |
DOI's | |
Status | Published - mrt.-1990 |