Synthesis and ligand exchange reactions of (pentamethylcyclopentadienyl)lanthanum aryloxides

H.J. Heeres, J.H. Teuben

OnderzoeksoutputAcademicpeer review

12 Citaten (Scopus)

Samenvatting

Cp*La(OAr)2 (Cp* = η5-C5Me5) is easily accessible by the reaction of La(OAr)3 with Cp*Li. Addition of THF yields the adduct Cp*La(OAr)2(THF)2. Both compounds disproportionate in solution with formation of equilibrium mixtures with comparable amounts of Cp*La(OAr)2, La(OAr)3 and Cp*2LaOAr. The equilibria were studied at various temperatures and thermodynamic parameters were determined from the temperature dependence of the equilibrium constants.
Originele taal-2English
Pagina's (van-tot)226-229
Aantal pagina's4
TijdschriftRecueil des Travaux Chimiques des Pays-Bas-Journal of the Royal Netherlands Chemical Society
Volume109
Nummer van het tijdschrift3
DOI's
StatusPublished - mrt.-1990

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