Samenvatting
Herein we present the first example of a glycol-coordinated ϵ-Keggin Al13 chloride (gl-ϵ-Al13), which is the first chelated version since discovery of Al13 in 1960. The molecular structure consists of [AlO4Al12(OH)12(OC2H4OH)12]Cl7·H2O units with chelating mono-anionic ethylene glycol units replacing one bridging and one terminal oxygen site.
Originele taal-2 | English |
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Pagina's (van-tot) | 4148-4151 |
Aantal pagina's | 4 |
Tijdschrift | Chemical Communications |
Volume | 54 |
Nummer van het tijdschrift | 33 |
DOI's | |
Status | Published - 1-jan.-2018 |
Vingerafdruk
Duik in de onderzoeksthema's van 'Synthesis, characterization and properties of a glycol-coordinated ϵ-Keggin-type Al13 chloride'. Samen vormen ze een unieke vingerafdruk.Datasets
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CCDC 1813736: Experimental Crystal Structure Determination
Gu, B. (Contributor), Sun, C. (Contributor), Fettinger, J. C. (Contributor), Casey, W. H. (Contributor), Dikhtiarenko, A. (Contributor), Gascon, J. (Contributor), Koichumanova, K. (Contributor), Babu Sai Sankar Gupta, K. (Contributor), Jan Heeres, H. (Contributor) & He, S. (Contributor), University of Groningen, 22-dec.-2017
DOI: 10.5517/ccdc.csd.cc1ywbms
Dataset