Synthesis of Amphiphilic Poly(2-(1-Pyrrolidonyl)-Ethylvinylether-b-Isobutylvinylether)

O. Nuyken; G. Rieß; J.A. Loontjens; R. van der Linde

Synthesis of Amphiphilic Poly(2-(1-Pyrrolidonyl)-Ethylvinylether-b-Isobutylvinylether)

O. Nuyken, G. Rieß, J.A. Loontjens, R. van der Linde

Zernike Institute for Advanced Materials

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Block copolymers consisting of isobutyl vinylether (IBVE) and 2-(1-pyrrolidonyl)-ethylvinylether (PEVE) were synthesized by the nucleophilic substitution of poly(2-chloroethylvinylether-b-isobutylvinylether) (poly(CEVE-b-IBVE)) by the anion of pyrrolidone. The poly(CEVE-b-IBVE) was obtained by sequential polymerization of CEVE and IBVE initiated by 1-iodo-1-(2-methylpropyloxy)ethane/tetrabutylammonium perchlorate. The molar mass and the composition of the block copolymer can be controlled, because the polymerization shows the characteristics of a living polymerization.

Originele taal-2	English
Pagina's (van-tot)	459-466
Aantal pagina's	8
Tijdschrift	Journal of Macromolecular Science. Part A: Pure and Applied Chemistry
Volume	32
Nummer van het tijdschrift	2
Status	Published - 1995

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title = "Synthesis of Amphiphilic Poly(2-(1-Pyrrolidonyl)-Ethylvinylether-b-Isobutylvinylether)",

abstract = "Block copolymers consisting of isobutyl vinylether (IBVE) and 2-(1-pyrrolidonyl)-ethylvinylether (PEVE) were synthesized by the nucleophilic substitution of poly(2-chloroethylvinylether-b-isobutylvinylether) (poly(CEVE-b-IBVE)) by the anion of pyrrolidone. The poly(CEVE-b-IBVE) was obtained by sequential polymerization of CEVE and IBVE initiated by 1-iodo-1-(2-methylpropyloxy)ethane/tetrabutylammonium perchlorate. The molar mass and the composition of the block copolymer can be controlled, because the polymerization shows the characteristics of a living polymerization.",

author = "O. Nuyken and G. Rie{\ss} and J.A. Loontjens and Linde, {R. van der}",

note = "Relation: http://www.rug.nl/zernike/ Rights: University of Groningen, Zernike Institute for Advanced Materials",

year = "1995",

language = "English",

volume = "32",

pages = "459--466",

journal = "Journal of Macromolecular Science. Part A: Pure and Applied Chemistry",

issn = "1060-1325",

number = "2",

}

TY - JOUR

T1 - Synthesis of Amphiphilic Poly(2-(1-Pyrrolidonyl)-Ethylvinylether-b-Isobutylvinylether)

AU - Nuyken, O.

AU - Rieß, G.

AU - Loontjens, J.A.

AU - Linde, R. van der

N1 - Relation: http://www.rug.nl/zernike/ Rights: University of Groningen, Zernike Institute for Advanced Materials

PY - 1995

Y1 - 1995

N2 - Block copolymers consisting of isobutyl vinylether (IBVE) and 2-(1-pyrrolidonyl)-ethylvinylether (PEVE) were synthesized by the nucleophilic substitution of poly(2-chloroethylvinylether-b-isobutylvinylether) (poly(CEVE-b-IBVE)) by the anion of pyrrolidone. The poly(CEVE-b-IBVE) was obtained by sequential polymerization of CEVE and IBVE initiated by 1-iodo-1-(2-methylpropyloxy)ethane/tetrabutylammonium perchlorate. The molar mass and the composition of the block copolymer can be controlled, because the polymerization shows the characteristics of a living polymerization.

AB - Block copolymers consisting of isobutyl vinylether (IBVE) and 2-(1-pyrrolidonyl)-ethylvinylether (PEVE) were synthesized by the nucleophilic substitution of poly(2-chloroethylvinylether-b-isobutylvinylether) (poly(CEVE-b-IBVE)) by the anion of pyrrolidone. The poly(CEVE-b-IBVE) was obtained by sequential polymerization of CEVE and IBVE initiated by 1-iodo-1-(2-methylpropyloxy)ethane/tetrabutylammonium perchlorate. The molar mass and the composition of the block copolymer can be controlled, because the polymerization shows the characteristics of a living polymerization.

M3 - Article

VL - 32

SP - 459

EP - 466

JO - Journal of Macromolecular Science. Part A: Pure and Applied Chemistry

JF - Journal of Macromolecular Science. Part A: Pure and Applied Chemistry

SN - 1060-1325

IS - 2

ER -