Synthesis of Poly(2-Chloro Ethyl Vinylether) and Its Derivatives

O. Nuyken, G. Rieß, J.A. Loontjens, R. van der Linde

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Samenvatting

The cationic polymerization of 2-chloro ethyl vinylether (CEVE) is initiated by 1-iodo-1-(2-methylpropyloxy)ethane/(n-Bu)4NClO4. The monomer is consumed following first order kinetics. Molar masses are controlled by the ratio [M]:[I]. A rather narrow molar mass distribution is obtained. These observations and the linear conversion-molar mass relationship indicate the living nature of the CEVE polymerization. Poly(CEVE) was converted into poly(2-(1-pyrrolidonyl)-1-ethylvinylether) by the complete nucleophilic substitution of chlorine by the anion of pyrrolidone.
Originele taal-2English
Pagina's (van-tot)217-226
Aantal pagina's10
TijdschriftJournal of Macromolecular Science. Part A: Pure and Applied Chemistry
Volume32
Nummer van het tijdschrift1
StatusPublished - 1995

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