Blockcopolymers consisting of N-vinylcarbazole (NVC) and isobutylvinylether (IBVE) were synthesized by sequential monomer addition. It is essential to start the synthesis with the NVC-segment and to initiate the polymerization by 1-iodo-1-(2-methylpropyloxy)ethane. The blockcopolymerization of IBVE proceeds only in the presence of an activator, such as (n-Bu)4NClO4. The blockcopolymers were characterized by GPC, 1H NMR, elemental analysis and DSC.
|Tijdschrift||Journal of Macromolecular Science. Part A: Pure and Applied Chemistry|
|Nummer van het tijdschrift||1|
|Status||Published - 1995|