TOXICOLOGICAL ANALYSIS OF WHOLE-BLOOD SAMPLES BY MEANS OF BOND-ELUT CERTIFY COLUMNS AND GAS-CHROMATOGRAPHY WITH NITROGEN-PHOSPHORUS DETECTION

  • PGM ZWEIPFENNING*
  • , AHCM WILDERINK
  • , P HORSTHUIS
  • , JP FRANKE
  • , RA DEZEEUW
  • *Corresponding author voor dit werk

OnderzoeksoutputAcademicpeer review

36 Citaten (Scopus)

Samenvatting

The application of Bond-Elut Certify solid-phase extraction columns to the systematic toxicological analysis of whole blood was evaluated. The reproducibility of the extraction was tested with thirteen drugs varying in physico-chemical properties. Analysis was performed with capillary gas chromatography with nitrogen-selective detection. The recoveries were reproducible, as long as other limiting factors, e.g., chromatographic behaviour or volatility, do not play a significant role. The effect of limiting chromatographic behaviour was studied in more detail with the more sensitive mass spectrometry with selected-ion monitoring after converting the extracted morphine into its ditrimethylsilyl derivative.

Originele taal-2English
Pagina's (van-tot)87-95
Aantal pagina's9
TijdschriftJournal of Chromatography A
Volume674
Nummer van het tijdschrift1-2
StatusPublished - 15-jul.-1994

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