Transition metal functionalized photo- and redox-switchable diarylethene based molecular switches

Emma C. Harvey; Ben L. Feringa; Johannes G. Vos; Wesley R. Browne; Mary T. Pryce

doi:10.1016/j.ccr.2014.06.008

Transition metal functionalized photo- and redox-switchable diarylethene based molecular switches

Emma C. Harvey, Ben L. Feringa, Johannes G. Vos, Wesley R. Browne^*, Mary T. Pryce

^*Corresponding author voor dit werk

Onderzoeksoutput › peer review

85 Citaten (Scopus)

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In this review recent progress in combining metal carbonyl and bipyridyl transition metal complexes with dithienylethene photochromic switches is discussed. A key challenge in designing such systems is to allow for interaction between the various components, but without loss in photochemical activity, i.e. the cyclization/cycloreversion of the dithienylethene unit. Examples of where the properties of the switching unit can be fine-tuned either photochemically or electrochemically by the addition of either bipyridyl transition metals or organometallic moieties to the switch will be highlighted. (C) 2014 Elsevier B.V. All rights reserved.

Originele taal-2	English
Pagina's (van-tot)	77-86
Aantal pagina's	10
Tijdschrift	Coordination Chemistry Reviews
Volume	282-283
DOI's	https://doi.org/10.1016/j.ccr.2014.06.008
Status	Published - 1-jan.-2015

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10.1016/j.ccr.2014.06.008

Transition metal functionalized photo- and redox-switchable diarylethene based molecular switchesFinal publisher's version, 1,43 MBLicentie: Taverne

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@article{0ec50278b56948e5ba27900f0e48f8e4,

title = "Transition metal functionalized photo- and redox-switchable diarylethene based molecular switches",

abstract = "In this review recent progress in combining metal carbonyl and bipyridyl transition metal complexes with dithienylethene photochromic switches is discussed. A key challenge in designing such systems is to allow for interaction between the various components, but without loss in photochemical activity, i.e. the cyclization/cycloreversion of the dithienylethene unit. Examples of where the properties of the switching unit can be fine-tuned either photochemically or electrochemically by the addition of either bipyridyl transition metals or organometallic moieties to the switch will be highlighted. (C) 2014 Elsevier B.V. All rights reserved.",

keywords = "Dithienylcyclopentene, Transition metals, Photocyclisation, Electrochromism, NLO, DITHIENYLETHENE DTE LINKER, ENERGY-TRANSFER PROCESSES, MAGNETIC INTERACTION, ELECTRONIC APPLICATIONS, PHOTOCHROMIC SWITCHES, COMPLEXES, DITHIENYLCYCLOPENTENES, BRIDGE, LUMINESCENCE, DERIVATIVES",

author = "Harvey, {Emma C.} and Feringa, {Ben L.} and Vos, {Johannes G.} and Browne, {Wesley R.} and Pryce, {Mary T.}",

year = "2015",

month = jan,

day = "1",

doi = "10.1016/j.ccr.2014.06.008",

language = "English",

volume = "282-283",

pages = "77--86",

journal = "Coordination Chemistry Reviews",

issn = "0010-8545",

publisher = "Elsevier Science",

}

TY - JOUR

T1 - Transition metal functionalized photo- and redox-switchable diarylethene based molecular switches

AU - Harvey, Emma C.

AU - Feringa, Ben L.

AU - Vos, Johannes G.

AU - Browne, Wesley R.

AU - Pryce, Mary T.

PY - 2015/1/1

Y1 - 2015/1/1

N2 - In this review recent progress in combining metal carbonyl and bipyridyl transition metal complexes with dithienylethene photochromic switches is discussed. A key challenge in designing such systems is to allow for interaction between the various components, but without loss in photochemical activity, i.e. the cyclization/cycloreversion of the dithienylethene unit. Examples of where the properties of the switching unit can be fine-tuned either photochemically or electrochemically by the addition of either bipyridyl transition metals or organometallic moieties to the switch will be highlighted. (C) 2014 Elsevier B.V. All rights reserved.

AB - In this review recent progress in combining metal carbonyl and bipyridyl transition metal complexes with dithienylethene photochromic switches is discussed. A key challenge in designing such systems is to allow for interaction between the various components, but without loss in photochemical activity, i.e. the cyclization/cycloreversion of the dithienylethene unit. Examples of where the properties of the switching unit can be fine-tuned either photochemically or electrochemically by the addition of either bipyridyl transition metals or organometallic moieties to the switch will be highlighted. (C) 2014 Elsevier B.V. All rights reserved.

KW - Dithienylcyclopentene

KW - Transition metals

KW - Photocyclisation

KW - Electrochromism

KW - NLO

KW - DITHIENYLETHENE DTE LINKER

KW - ENERGY-TRANSFER PROCESSES

KW - MAGNETIC INTERACTION

KW - ELECTRONIC APPLICATIONS

KW - PHOTOCHROMIC SWITCHES

KW - COMPLEXES

KW - DITHIENYLCYCLOPENTENES

KW - BRIDGE

KW - LUMINESCENCE

KW - DERIVATIVES

U2 - 10.1016/j.ccr.2014.06.008

DO - 10.1016/j.ccr.2014.06.008

M3 - Review article

SN - 0010-8545

VL - 282-283

SP - 77

EP - 86

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

ER -

Transition metal functionalized photo- and redox-switchable diarylethene based molecular switches

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