Ultrafast investigations of vibrationally hot molecules after internal conversion in solution

W. Wild; A. Seilmeier; N. H. Gottfried; W. Kaiser

doi:10.1016/0009-2614(85)80413-9

Ultrafast investigations of vibrationally hot molecules after internal conversion in solution

W. Wild, A. Seilmeier, N. H. Gottfried, W. Kaiser

Sterrenkunde

Onderzoeksoutput › Academic › peer review

64 Citaten (Scopus)

Samenvatting

The creation of vibrationally very hot molecules after internal conversion is seen for the first time in a liquid environment. Cooling of the excited molecules occurs within several 10 -11 s.Excitation of azulene with photons of 19000 cm -1 leads to a transient internal temperature of 1200 K. The excess population of vibrational modes of 700 cm -1 decays with a time constant of40 ps.

Originele taal-2	English
Pagina's (van-tot)	259-263
Tijdschrift	Astronomische Gesellschaft Abstract Series
Volume	119
Nummer van het tijdschrift	4
DOI's	https://doi.org/10.1016/0009-2614(85)80413-9
Status	Published - 1-sep-1985

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10.1016/0009-2614(85)80413-9

http://adsabs.harvard.edu/abs/1985CPL...119..259W

Citeer dit

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abstract = "The creation of vibrationally very hot molecules after internal conversion is seen for the first time in a liquid environment. Cooling of the excited molecules occurs within several 10 -11 s.Excitation of azulene with photons of 19000 cm -1 leads to a transient internal temperature of 1200 K. The excess population of vibrational modes of 700 cm -1 decays with a time constant of40 ps.",

author = "W. Wild and A. Seilmeier and Gottfried, {N. H.} and W. Kaiser",

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AU - Seilmeier, A.

AU - Gottfried, N. H.

AU - Kaiser, W.

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AB - The creation of vibrationally very hot molecules after internal conversion is seen for the first time in a liquid environment. Cooling of the excited molecules occurs within several 10 -11 s.Excitation of azulene with photons of 19000 cm -1 leads to a transient internal temperature of 1200 K. The excess population of vibrational modes of 700 cm -1 decays with a time constant of40 ps.

U2 - 10.1016/0009-2614(85)80413-9

DO - 10.1016/0009-2614(85)80413-9

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JO - Astronomische Gesellschaft Abstract Series

JF - Astronomische Gesellschaft Abstract Series

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